View Journal Article: Combinatorial Study of Surface Pattern Formation in Thin Block Copolymer Films
Citation:
Smith, Archie, Douglas, Jack, Meredith, J. Carson, Amis, Eric and Karim, Alamgir (2001). Combinatorial Study of Surface Pattern Formation in Thin Block Copolymer Films. Physical Review Letters87 (1). .
Surface pattern formation in diblock copolymer films is investigated as a function of film thickness h and molecular mass M. Smooth films are observed for certain h ranges centered
about multiples of the lamellar thickness L0, and we attribute this effect to an increase in the surface chain density with h in the outer brushlike copolymer layer. We also observe apparently
stable labyrinthine surface patterns for other h ranges, and the average size of these patterns is found to scale as these patterns is found to scale as l L22.50. Hole and island patterns occur for
h ranges between those of the labyrinthine patterns and the smooth regions, and their size similarly decreases with L0 and M.