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View Journal Article: Combinatorial Study of Surface Pattern Formation in Thin Block Copolymer Films

Citation: Smith, Archie, Douglas, Jack, Meredith, J. Carson, Amis, Eric and Karim, Alamgir (2001). Combinatorial Study of Surface Pattern Formation in Thin Block Copolymer Films. Physical Review Letters 87 (1). .
Collection: Polymer Publications  
 
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Title Combinatorial Study of Surface Pattern Formation in Thin Block Copolymer Films
Author(s) Smith, Archie
Douglas, Jack
Meredith, J. Carson
Amis, Eric
Karim, Alamgir
Keyword(s) combinatorial methods
diblock copolymer films
Surface pattern formation
labyrinthine surface patterns
Abstract/Summary Surface pattern formation in diblock copolymer films is investigated as a function of film thickness h and molecular mass M. Smooth films are observed for certain h ranges centered about multiples of the lamellar thickness L0, and we attribute this effect to an increase in the surface chain density with h in the outer brushlike copolymer layer. We also observe apparently stable labyrinthine surface patterns for other h ranges, and the average size of these patterns is found to scale as these patterns is found to scale as l L22.50. Hole and island patterns occur for h ranges between those of the labyrinthine patterns and the smooth regions, and their size similarly decreases with L0 and M.
Publisher The American Physical Society
Date 2001-02-07
Copyright Notice http://www.nist.gov/public_affairs/disclaim.htm
Journal Physical Review Letters
Volume 87
Issue 1
Copyright Agreement on
Additional Notes Physical Review Letters, Vol 87(1), (2001)
 
 
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